期刊
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
卷 31, 期 -, 页码 385-392出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2015.07.013
关键词
Biodiesel; Transesterification; Heterogeneous catalyst; Nano La2O3
资金
- Key Technologies RD Program [2011BAEO6B02]
- International Science &Technology Cooperation Program of China [2010DFB60840]
- Science and Technology Project of Guizhou Province [[2012]6012, [2011]3016]
A comparative study on the activity of La2O3 and two kinds of nano La2O3 catalysts prepared using sonochemical (nano La2O3-S) and hydrothermal methods in the transesterification to produce biodiesel was conducted. The relatively high activity of nano La2O3 catalysts may be ascribed to their high base strength, large base amount, small particle size and large BET surface areas. Nano La2O3-S was selected for further optimisation due to its simple preparation procedure and short preparation time. The FAME content and yield obtained were successively 97.6% and 90.3% under optimal conditions. Moreover, nano La2O3-S showed a remarkable tolerance to FFA. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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