期刊
CHINESE JOURNAL OF POLYMER SCIENCE
卷 32, 期 4, 页码 509-518出版社
SPRINGER
DOI: 10.1007/s10118-014-1417-x
关键词
Polypropylene; Composite; Mechanical property; Interfacial morphology
资金
- National Natural Science Foundation of China [50833006, 21274009, 51221002]
Matrix/fiber composites of beta-form isotactic polypropylene (iPP) matrix and alpha-iPP or PA6 fibers were prepared by laminating technique under different preparation temperatures. The mechanical properties and interfacial morphologies of these composites were studied by tensile test, optical microscopy and scanning electron microscopy, respectively. The experimental results show that the tensile yield load and tensile modulus of beta-iPP/PA6 matrix/fiber systems increased significantly at the expense of elongation at break. These mechanical properties show essentially no dependence on the sample preparation temperature. On the other hand, the mechanical properties of iPP matrix/fiber single polymer composites depend strongly on the sample preparation temperature. At low sample preparation temperature, e.g., 172 A degrees C, the solid alpha-iPP fiber induces alpha-iPP crystallization, leading to the formation of alpha-iPP transcrystalline layer around the fiber. This results in a remarkable increment of the tensile yield load and tensile modulus. The elongation at break is also much better than that of the iPP/PA6 matrix/fiber system. It reflects a better interfacial adhesion of the single polymer composite compared with the iPP/PA6 composite. At higher sample preparation temperature, e.g., 174 A degrees C or 176 A degrees C, the partial surface melting of the oriented fiber allows interdiffusion of iPP molecular chains in the molten fiber and matrix melt. The penetration of matrix chains into the molten iPP fiber results in some iPP molecular chains being included partially in the recrystallized fiber and the induced beta-transcrystalline layers. This kind of configuration leads to an improvement of interfacial adhesion between the fiber and matrix, which causes a simultaneous increase of the tensile yield load, tensile modulus and elongation at break of beta-iPP.
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