期刊
CHINESE JOURNAL OF POLYMER SCIENCE
卷 27, 期 2, 页码 145-148出版社
SPRINGER
DOI: 10.1142/S0256767909003765
关键词
Regioregular; Click chemistry; Polycyclotrimerization; Hyperbranched polymer
资金
- National Natural Science Foundation of China [20634020, 50703033]
- Ministry of Science Technology [2009CB623605]
- Research Grants Council of Hong Kong [603008, 602707, 602706]
- China Postdoctoral Science Foundation [20070420228]
- Cao Guangbiao Foundation of Zhejiang University
A new bis(aroylacetylene) containing triazole and fluorene moieties is synthesized by click chemistry. Polycyclotrimerization of the monomer is catalyzed by piperidine in refluxed dioxane, furnishing a regioregular poly(aroylarylene) in a satisfactory yield. The hyperbranched structure of the polymer is characterized spectroscopically with satisfactory results. The polymer enjoys no metal detriment and is soluble in common organic solvents such as tetrahydrofuran (THF), chloroform, dichloromethane (DCM), and N,N-dimethylformamide (DMF).
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