期刊
CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 34, 期 6, 页码 1177-1182出版社
SCIENCE PRESS
DOI: 10.6023/cjoc201308020
关键词
alpha-oxindole-phosphonates; isatins; H-phosphonates; Brook rearrangement; cascade reaction
资金
- National Natural Science Foundation of China [21272166]
- Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions [13KJA150004]
A cascade phospho-aldol-Brook rearrangement reaction of isatins with H-phosphonates was reported by the use of the organic base, such as 1,1,3,3-tetramethylguanidine (TMG) or 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), as an organo-catalyst. Two series of 2-oxoindolin-3-yl phosphates were obtained in good to excellent yields under mild reaction conditions.
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