期刊
CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 34, 期 4, 页码 717-721出版社
SCIENCE PRESS
DOI: 10.6023/cjoc201312023
关键词
AgNO3; P-radical; isonitrile; C-P bond
资金
- National Natural Science Foundation of China [21272100]
A simple and efficient method for the cyclization of the addition of P-radical to 2-isocyano-1,1'-biphenyl by employing silver salt as an oxidant was developed. The high atom economy, mild reaction system and a wide range of substrates with high yields make the protocol very practical. It provides a new route for C P bond formation. A series of 6-phosphorylated phenanthridines were synthesized.
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