期刊
CHINESE JOURNAL OF CHEMISTRY
卷 36, 期 11, 页码 1075-1109出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201800314
关键词
hydrometallation; the first row transition metals; alkenes; alkynes; metal-hydride
资金
- National Natural Science Foundation of China [21772171]
- National 973 Program [2015CB856600]
- Fundamental Research Funds for the Central Universities [2018QNA3009]
- Thousand Youth Talents Plan
Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl- or alkenyl-metal reagents, which have a wide range of applications in organic transformations. In recent years, the first row transition metals (such as copper, nickel, cobalt, iron, etc.) have emerged high activity and selectivity in this area with the aid of a variety of ligands. This review covers the recent advances in the hydrometallation of minimally functionalized unsaturated CC bonds (including alkenes, alkynes, dienes, allenes, enynes, etc.), as well as transformations involving catalytic hydrometallation process via the first row transition metal catalysis.
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