期刊
CHINESE JOURNAL OF CHEMISTRY
卷 32, 期 10, 页码 1003-1006出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201400419
关键词
diphenyl phosphite; hydrophosphonylation; N-tert-butanesulfinyl ketimine; diastereoselectivity; Pudovik reaction
资金
- National Natural Science Foundation of China [21172243]
The asymmetric Pudovik reaction of chiral fluoroalkyl ,-unsaturated ketimines derivated from (R)-tert-butanesulfinamide and diphenyl phosphite was achieved in the presence of Rb2CO3 at room temperature. A series of fluoroalkylated -amino phosphonates were prepared in good yields with high diastereoselectivities.
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