期刊
CHINESE JOURNAL OF CHEMISTRY
卷 32, 期 10, 页码 937-956出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201400428
关键词
Au catalyst; Bronsted acid; Lewis acid; relay catalysis; Tandem reaction
资金
- Natural Science Foundation of China [21102085]
- Fundamental Research Funds of Shandong University [2014JC008]
- Subject Construction Funds of Shandong University [104.205.2.5]
Recently, homogeneous gold catalysis has attracted tremendous attention and has also been widely used in multistep synthesis. The current reaction methodology starts from the gold activation of unsaturated carbon bond and subsequent nucleophilic attack. The combination of a gold catalyst with another acid catalyst, including Bronsted acid and Lewis acid, is possible to bring two distinctive catalytic systems together and deliver unprecedented new reactions. More essentially, it avoids the purification of unstable intermediates and improves the step and atom economy. Here, the recent progress in the Au/Acid combined catalysis is reviewed, including the scope of reactions, mechanism and synthetic applications.
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