期刊
CHINESE JOURNAL OF CHEMISTRY
卷 32, 期 8, 页码 803-813出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201400409
关键词
asymmetric catalysis; hydrogenation; ruthenium; sulfone; 1,5-diol
Chiral molecules containing sulfonyl and 1,5-diol moieties are useful synthetic blocks for various asymmetric transformations. A protocol has been developed for the enantioselective synthesis of optically active bis(beta-hydroxy) sulfones catalyzed by a chiral cationic ruthenium diamine catalyst. A series of bis(beta-hydroxy) sulfones have been obtained in excellent yields (up to 99%) with excellent enantioselectivities (up to 99%) as well as good diastereoselectivities (up to 99 : 1).
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