期刊
CHINESE JOURNAL OF CHEMISTRY
卷 31, 期 4, 页码 479-484出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201300094
关键词
domino reaction; electron-deficient alkyne; acrylate; isatin; stereoselectivity
资金
- National Natural Science Foundation of China [21172189]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
The functionalized arylidene bis(3-arylaminoacrylates) were efficiently prepared by FeCl3 catalyzed one-pot domino reactions of primary amines, methyl propiolate and aromatic aldehydes. When isatins were utilized under similar conditions, only 2-oxoindolinyl 3-arylaminoacrylates were obtained in moderate yields. 1H NMR data and single crystal structures indicated that this reaction has high diastereoselectivity.
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