期刊
CHINESE JOURNAL OF CHEMISTRY
卷 31, 期 1, 页码 37-39出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201200994
关键词
ss-keto acids; isochromans; 2,2,6-6-tetramethylpiperdine-1-oxoammonium salts; decarboxylation; alkylation
资金
- National Natural Science Foundation of China [21232007, 21172206]
- National Basic Research Program of China (973 Program) [2010CB833300]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1189]
An unprecedented decarboxylative alkylation reaction of beta-keto acids with isochromans has been developed under oxidative conditions. A range of beta-keto acids smoothly undergo decarboxylative alkylation with isochromans in the presence of 2,2,6,6-tetramethylpiperdine-1-oxoammonium hexafluorophosphate to give structurally diverse 1-acylmethylisochromans in moderate to excellent yields with extremely high regioselectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
