期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 52, 页码 15859-15862出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201509218
关键词
boration; Bronsted bases; diborylalkenes; organocatalysis; synthetic methods
资金
- JSPS [15H03803]
- CREST, JST
- Grants-in-Aid for Scientific Research [13J03459, 15H03803] Funding Source: KAKEN
A method for the synthesis of 1,1-diborylalkenes through a Bronsted base catalyzed reaction between terminal alkynes and bis(pinacolato)diboron has been developed. The procedure allows direct synthesis of functionalized 1,1-diborylalkenes from various terminal alkynes including propiolates, propiolamides, and 2-ethynylazoles.
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