期刊
CHINESE JOURNAL OF CHEMISTRY
卷 31, 期 2, 页码 271-276出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201200741
关键词
copper ion; colorimetric sensor; biscarbonyl hydrazone; single selectivity
资金
- National Natural Science Foundation of China (NSFC) [21064006, 21161018]
- Natural Science Foundation of Gansu Province [1010RJZA018]
- Program for Changjian Scholars and Innovative Research Team in University of Minisry of Education of China [IRT1177]
A novel copper selective sensor 2 based on hydrazide and salicylaldehyde has been designed and prepared. Sensor 2 behaves a single selectivity and sensitivity in the recognition for Cu2+ over other metal ions such as Fe3+, Hg2+, Ag+, Ca2+, Zn2+, Pb2+, Cd2+, Ni2+, Co2+, Cr3+ and Mg2+ in DMSO. The distinct color change and the rapid changement of fluorescence emission provide naked-eyes detection for Cu2+. The UV-vis data indicate that 1:2 stoichiometry complex is formed by sensor 2 and Cu2+. The association constant Ks was 3.51x104 mol1 center dot L. The detection limitation of Cu2+ with the sensor 2 was 2.2x107 mol center dot L1. The sensing of Cu2+ by this sensor was found to be reversible, with the Cu2+-induced color being lost upon addition of EDTA.
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