期刊
CHINESE JOURNAL OF CHEMISTRY
卷 29, 期 12, 页码 2717-2721出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201100325
关键词
difluorocarbene; CF2H group; difluoromethylation; difluoromethyltri(n-butyl)ammonium chloride
资金
- National Natural Science Foundation of China [20772144, 20825209, 20832008]
- Chinese Academy of Sciences
Difluoromethyltri(n-butyl)ammonium chloride 1 was found to be an effective difluorocarbene reagent for O-, S-, N-, C-difluoromethylation under basic conditions. It is particularly remarkable that, when only 1.2 equivalent of reagent 1 was used, the difluoromethylated products were obtained in moderate to excellent yields.
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