期刊
CHINESE JOURNAL OF CHEMISTRY
卷 28, 期 1, 页码 86-90出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201090040
关键词
diethylstilbestrol; high performance liquid chromatography; fluorescence detection; aquatic product
资金
- Programs for Science and Technology Development of Shandong Province of China [2008GG10005005]
- Oceanic Research Fundation [200805031]
A sensitive method for the determination of diethylstilbestrol (DES) in aquatic products by high performance liquid chromatography (HPLC) using a fluorescence detector (FLD) was developed. By means of sulfonation in concentrated Sulfuric acid and hydrolysis, DES was converted into a reaction product that can emit fluorescence and determined by HPLC. For the first time, HPLC with FLD was applied to the determination of DES and sensitivity comparable to that of LC-MS gained. The limit of detection was 0.1 mu g.kg(-1), and the recoveries were above 86% with relative standard deviations less than 6.2%. The proposed method was successfully applied to the determination of DES in aquatic products.
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