期刊
CHINESE CHEMICAL LETTERS
卷 25, 期 6, 页码 907-911出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2014.04.031
关键词
Fuel cell; Ternary alloy; Formic acid oxidation; Methanol electro-oxidation
资金
- NSFC [21373116]
- Tianjin Natural Science Research Fund [13JCYBJC18300]
- RFDP [20120031110005]
- MOE Innovation Team of China [IRT13022]
Pt:Pd:Co ternary alloy nanoparticles were synthesized by sodium borohydride reduction under nitrogen, and were supported on carbon black as catalysts for methanol and formic acid electro-oxidation. Compared with Pt0.65Co0.35, Pt/C, Pd0.65Co0.35/C, and Pd/C catalyst, Pt0.35Pd0.35Co0.30/C exhibited relatively high durability and strong poisoning resistance, and the Pt-mass activity was 3.6 times higher than that of Pt/C in methanol oxidation reaction. Meanwhile, the Pt0.35Pd0.35Co0.30/C exhibited excellent activity with higher current density and higher CO tolerance than that of Pt0.65Co0.35/C, Pt/C, Pd0.65Co0.35/C, and Pd/C in formic acid electro-oxidation. (C) 2014 Tie-Hong Chen. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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