期刊
CHINESE CHEMICAL LETTERS
卷 24, 期 8, 页码 707-709出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2013.05.008
关键词
Molecular recognition; Pillararenes; Unsaturated hydrocarbons; Supramolecular chemistry
资金
- NNSFC [21272155, 21272147]
- Innovation Program of Shanghai Municipal Education Commission [13YZ010]
The complexation behavior of unsaturated fatty hydrocarbons, i.e., 1,7-octadiyne and 1,7-octadiene, by a perethylated pillar[5]arene has been investigated, which was compared with that for saturated n-octane. It was found that the host-guest binding strength increased in accordance with the electron-negativity of the terminal carbon atom on the guests: allcyne > alkene > alkane. (C) 2013 Chun-Ju Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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