期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 1, 页码 345-349出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201508294
关键词
C-C activation; copper; cyanation; dearomatization; sigmatropic rearrangement
资金
- National Institutes of Health [GM46059]
A copper-catalyzed borylation/ortho-cyanation/allyl group transfer cascade was developed. Initiated by an unconventional copper-catalyzed electrophilic dearomatization, this process features regio- and stereospecific 1,3-transposition of the allyl fragment enabled by an aromatization-driven Cope rearrangement. This method provides an effective means for the construction of adjacent tertiary and quaternary stereocenters with excellent diastereocontrol.
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