期刊
CHINESE CHEMICAL LETTERS
卷 23, 期 6, 页码 631-634出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2012.03.022
关键词
Lewis acid; Seleno-arylation; Succinimidyl selenide; Solid-phase synthesis; Dihydrocoumarins; Coumarins
资金
- National Natural Science Foundation of China [20802063, 21162032]
- Foundation of the Key Laboratory of Medicinal Chemistry of Natural Resource (Yunnan University), Ministry of Education, China
TMSOTf-catalyzed intramolecular seleno-arylation of tethered alkenes was performed using polystyrene-supported succinimidyl selenide as the selenium source. This catalytic process provides an efficient method for the regioselective synthesis of dihydrocoumarins possessing a seleno-functionality, followed by traceless cleavage of selenium linker to provide dihydrocoumarins and coumarins in good yields and purities. (C) 2012 E Tang. Published by Elsevier B.V on behalf of Chinese Chemical Society. All rights reserved.
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