Synthesis of new indolyl crown ethers catalyzed with ferric hydrogensulfate

Efficient reaction of bis-indolyl podand with different aldehydes using Fe(HSO4)(3) as catalyst to afford the corresponding new indolyl crown ethers is described. The structures of three distinct isomers have been optimized using HyperChem geometry optimizations. Also percentage of each isomer was obtained with H-1 NMR spectroscopy. (C) 2012 Hossein Eshghi. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.