4.7 Article

Synergistic catalysis of isolated Fe3+ and Fe2O3 on FeOx/HZSM-5 catalysts for Friedel Crafts benzylation of benzene

期刊

CHINESE CHEMICAL LETTERS
卷 22, 期 6, 页码 639-642

出版社

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2010.12.034

关键词

Friedel Crafts; Synergistic catalysis; Benzene; Diphenylmethane; Fe3+; FeOx./HZSM-5

资金

  1. Ministry of Education [NCET-10-878, 20096101120018]
  2. Shaanxi Province [2009ZDKG-70, 09JK793]
  3. Northwest University [PR200905]
  4. State Key Lab for SSPC

向作者/读者索取更多资源

FeOx/HZSM-5 catalyst with 8 wt.% Fe-loading (8-FeZ) exhibited significantly higher reactivity in the benzylation of benzene with benzyl chloride than FeOx/HZSM-5 catalyst with 2.5 wt.% Fe-loading (2.5-FeZ) because the synergistic catalysis between isolated Fe3+ and superfine Fe2O3 occurred on 8-FeZ in the reaction. (C) 2010 Xin Zhang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

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