期刊
CHINESE CHEMICAL LETTERS
卷 21, 期 3, 页码 312-316出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2009.11.040
关键词
Hydrosilylation; Terminal alkynes; Tri(t-butyl)phosphine; Platinum
A highly efficient and regio-/stereoselective method of hydrosilylating terminal alkynes was developed using Pt(DVDS)-tri(t-butyl)phosphine catalyst system at room temperature. Trans-products or alpha-products were obtained almost exclusively depending on the alkynes and silanes employed. (C) 2009 Wei Wu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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