期刊
CHINESE CHEMICAL LETTERS
卷 19, 期 11, 页码 1301-1304出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2008.07.019
关键词
Alkyl thiocyanate; Alkyl halide; Tetrabutylammonium bromide; Phase transfer catalyst; Synthesis of alkyl thiocyanates
资金
- Chamran University Research Council
A simple and environmentally friendly method is described for the efficient conversion of alkyl halide to alkyl thiocyanate using tetrabutylammonium bromide (TBAB) as a phase transfer catalyst. The reactions occur in water and furnish the corresponding alkyl thiocyanate in high yields. No evidence for the formation of isothiocyanates as by-product of the reaction was observed and the products were obtained in pure form without further purification. (C) 2008 Ali Reza Kiasat. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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