期刊
CHIMIA
卷 66, 期 6, 页码 399-403出版社
SWISS CHEMICAL SOC
DOI: 10.2533/chimia.2012.399
关键词
Cyclisations; Radicals; Reductions; Samarium; Water
资金
- EPSRC [EP/H008691/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H008691/1] Funding Source: researchfish
Recent work from our laboratories has shown SmI2-H2O to be a versatile, readily-accessible and nontoxic reductant that is more powerful than SmI2. This review describes the reduction of functional groups that were previously thought to lie beyond the reach of SmI2 and complexity-generating cyclisations and cyclisation cascades triggered by the reduction of the ester carbonyl group with SmI2-H2O.
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