4.1 Article

Recent Advances in the Chemistry of SmI2-H2O

期刊

CHIMIA
卷 66, 期 6, 页码 399-403

出版社

SWISS CHEMICAL SOC
DOI: 10.2533/chimia.2012.399

关键词

Cyclisations; Radicals; Reductions; Samarium; Water

资金

  1. EPSRC [EP/H008691/1] Funding Source: UKRI
  2. Engineering and Physical Sciences Research Council [EP/H008691/1] Funding Source: researchfish

向作者/读者索取更多资源

Recent work from our laboratories has shown SmI2-H2O to be a versatile, readily-accessible and nontoxic reductant that is more powerful than SmI2. This review describes the reduction of functional groups that were previously thought to lie beyond the reach of SmI2 and complexity-generating cyclisations and cyclisation cascades triggered by the reduction of the ester carbonyl group with SmI2-H2O.

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