期刊
CHIMIA
卷 66, 期 11, 页码 869-872出版社
SWISS CHEMICAL SOC
DOI: 10.2533/chimia.2012.869
关键词
Asymmetric catalysis; C-H Activation; Ligands; Palladium; Rhodium
资金
- ETH Zurich
- EPF Lausanne
- Swiss National Science Foundation
- 'Stipendien Fonds der Chemischen Industrie'
- European Union through an ERC Starting Grant
The direct functionalization of non-activated C-H bonds, especially in an enantioselective manner, requires metal catalysts equipped with ligands with specifically designed properties. Examples for asymmetric C(sp(2))-H and C(sp(3))-H functionalizations using palladium- and rhodium catalysts are shown. This work was rewarded by the 2012 Werner Prize of the Swiss Chemical Society.
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