期刊
CHIMIA
卷 64, 期 4, 页码 247-251出版社
SWISS CHEMICAL SOC
DOI: 10.2533/chimia.2010.247
关键词
Homogeneous catalysis; Gold; Propargylic carboxylates; Ring expansions
资金
- Swiss National Science Foundation, Givaudan AG
- Organic Chemistry Institute of the University of Zurich
The field of homogeneous gold catalysis has developed exponentially over the past ten years. Even if the array of gold-mediated transformations is extremely broad, a common feature stems from the ability of gold to activate unsaturated moieties due to the strong relativistic effects governing its coordination behavior. Starting with a short historical perspective, this review compiles the recent advances in two fundamental areas: first, the rearrangement of propargylic carboxylates and second, ring-expansion processes, both topics of interest in our research group at the Organic Chemistry Institute of the University of Zurich.
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