期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 37, 页码 10792-10796出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201503553
关键词
buckybowl-graphene hybrids; fused-ring systems; polyaromatic hydrocarbons; structure-activity relationships
资金
- National Basic Research Program of China [2015CB856500]
- Qian Ren Scholar Program of China
- Synergetic Innovation Center of Chemical Science and Engineering (Tianjin)
- Swiss National Science Foundation
Among sheet/sheet polynuclear aromatic hydrocarbon (PAH) hybrids, a buckybowl-graphene hybrid has been used as a model to explore the effects of physical properties of PAHs with distinct planar and bowl regions. Activation of a C(Ar)F bond was used to synthesize this corannulene/graphenic hybrid. Photophysical and voltammetric studies together with high-level computations revealed curvature and extended -effects on the properties of these materials.
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