期刊
CHEMSUSCHEM
卷 7, 期 8, 页码 2070-2080出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201402322
关键词
energy storage; homogeneous catalysis; oxidation; transition metals; water chemistry
资金
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan [24350029, 2107, 24108732, 2406, 24107004]
- International Institute for Carbon Neutral Energy Research (WPI-I2CNER) - World Premier International Research Center Initiative (WPI), MEXT, Japan
- Grants-in-Aid for Scientific Research [24108732, 24107004] Funding Source: KAKEN
This minireview provides a brief overview of the progress that has been made in developing homogeneous water oxidation catalysts based on base metals (manganese, iron, cobalt, nickel, and copper) from the 1990s to mid-2014. The impact of each contribution is analyzed, and opportunities for further improvement are noted. In addition, the relative stabilities of the base-metal catalysts that have been reported are compared to illustrate the importance of developing more robust catalytic systems by using these metals. This manuscript is intended to provide a firm foundation for researchers entering the field of water oxidation based on base metals and a useful reference for those currently involved in the field.
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