期刊
CHEMSUSCHEM
卷 8, 期 2, 页码 269-274出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201402761
关键词
5-hydroxymethylfurfural; biomass; carbohydrates; catalysis; choline chloride
资金
- CNRS
- University of Poitiers
- French Ministry of Research
- China Scholarship Council (CSC)
- National Natural Science Foundation of China [21373093]
- Fundamental Research Funds for the Central Universities of China [2014ZZGH019]
We show that the coating of choline chloride on silica-supported AlCl3 allows the dehydration of carbohydrates to successfully proceed in low boiling point organic solvents. The concept is based on the in situ formation of a deep eutectic liquid phase on the catalyst surface, thus facilitating the interaction between the solid catalyst and insoluble carbohydrate.
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