期刊
CHEMSUSCHEM
卷 7, 期 4, 页码 1094-1101出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201301061
关键词
capacitors; electrochemistry; nanostructures; polymers; renewable resources
资金
- Energy Efficiency & Resources of the Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Korea government Ministry of Knowledge Economy [20122010100140]
- National Research Foundation (NRF)
- Korean Government (MEST) [20090063004]
- Korea Institute of Science & Technology (KIST) institutional program
- Nanostructures for Electrical Energy Storage (NEES), an Energy Frontier Research Center
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DESC000116]
- [NRF-2010-C1AAA001-0029018]
Strong demand for high-performance energy-storage devices has currently motivated the development of emerging capacitive materials that can resolve their critical challenge (i.e., low energy density) and that are renewable and inexpensive energy-storage materials from both environmental and economic viewpoints. Herein, the pseudocapacitive behavior of lignin nanocrystals confined on reduced graphene oxides (RGOs) used for renewable energy-storage materials is demonstrated. The excellent capacitive characteristics of the renewable hybrid electrodes were achieved by synergizing the fast and reversible redox charge transfer of surface-confined quinone and the interplay with electron-conducting RGOs. Accordingly, pseudocapacitors with remarkable rate and cyclic performances (approximate to 96% retention after 3000cycles) showed a maximum capacitance of 432Fg(-1), which was close to the theoretical capacitance of 482Fg(-1) and sixfold higher than that of RGO (93Fg(-1)). The chemical strategy delineated herein paves the way to develop advanced renewable electrodes for energy-storage applications and understand the redox chemistry of electroactive biomaterials.
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