期刊
CHEMSUSCHEM
卷 7, 期 11, 页码 3157-3163出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201402584
关键词
diester; hydroesterification; isosorbide; olefin; palladium
资金
- ANR [2010-006-01]
The hydroesterification of alpha olefins has been used to synthesize diesters from bio-based secondary diols: isosorbide, isomannide, and isoidide. The reaction was promoted by 0.2% palladium catalyst generated insitu from palladium acetate/triphenylphosphine/para-toluene sulfonic acid. Optimized reaction conditions allowed the selective synthesis of the diesters with high yields and the reaction conditions could be scaled up to the synthesis of hundred grams of diesters from isosorbide and 1-octene with solvent-free conditions.
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