期刊
CHEMSUSCHEM
卷 6, 期 4, 页码 652-658出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201200842
关键词
biomass; homogeneous catalysis; hydrogenation; nickel; tungsten
资金
- 973 Program of China [2009CB226102]
- National Science Foundation of China [20903089, 21003121, 21176235]
Following our previous report on the selective transformation of cellulose to ethylene glycol (EG) over a binary catalyst composed of tungstic acid and Ru/C, we herein report a new low-cost but more effective binary catalyst by using Raney nickel in place of Ru/C (Raney Ni+H2WO4). In addition to tungstic acid, other W compounds were also investigated in combination with Raney Ni. The results showed that the EG yield depended on the W compound: H4SiW12O40
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