期刊
CHEMSUSCHEM
卷 4, 期 10, 页码 1407-1419出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201100050
关键词
adsorption; green chemistry; heterogeneous catalysis; organic-inorganic hybrid composites; phosphorus
资金
- National Natural Science Foundation of China [20973096, 21073099]
- National Basic Research Program of China [2009CB623502]
- Natural Science Foundation of Tianjin [08 JCZDJC21500]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0927]
The synthesis of porous hybrid materials has been extended to mesoporous non-silica-based organic-inorganic hybrid materials, in which mesoporous metal phosphonates represent an important family. By using organically bridged polyphosphonic acids as coupling molecules, the homogeneous incorporation of a considerable number of organic functional groups into the metal phosphonate hybrid framework has been realized. Small amounts of organic additives and the pH value of the reaction solution have a large impact on the morphology and textural properties of the resultant hybrid mesoporous metal phosphonate solids. Cationic and nonionic surfactants can be used as templates for the synthesis of ordered mesoporous metal phosphonates. The materials are used as efficient adsorbents for heavy metal ions, CO2, and aldehydes, as well as in the separation of polycyclic aromatic hydrocarbons. They are also useful photocatalysts under UV and simulated solar light irradiation for organic dye degradation. Further functionalization of the synthesized mesoporous hybrids makes them oxidation and acid catalysts, both with impressive performances in the fields of sustainable energy and environment.
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