期刊
CHEMSUSCHEM
卷 4, 期 1, 页码 112-118出版社
WILEY-BLACKWELL
DOI: 10.1002/cssc.201000231
关键词
alcohols; biomass; heterogeneous catalysis; solvolysis; sustainable chemistry
资金
- National High-Tech Research and Development Program of China [2007AA05Z403]
- CAS [KGCXZ-YW-336]
A clean, facile, and environment-friendly catalytic method has been developed for the conversion of furfuryl alcohol into alkyl levulinates making use of the novel solid catalyst methylimidazolebutylsulfate phosphotungstate ([MIMBS](3)PW(12)O(40)). The solid catalyst is an organic-inorganic hybrid material, which consists of an organic cation and an inorganic anion. A study for optimizing the reaction conditions such as the reaction time, the temperature and the catalyst loading has been performed. Under optimal conditions, a high n-butyl levulinate yield of up to 93% is obtained. Furthermore, the kinetics of the reaction pathways and the mechanism for the alcoholysis of furfuryl alcohol are discussed. This method is environmentally benign and economical for the conversion of biomass-based derivatives into fine chemicals.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据