期刊
CHEMSUSCHEM
卷 1, 期 11, 页码 927-933出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.200800152
关键词
catalyst recycling; homogeneous catalysis; membranes; metathesis; ruthenium
This study was aimed at integrating a green separation process without phase change, namely nanofiltration, with olefin metathesis to recover the homogeneous catalyst. As the commercially available Hoveyda II catalyst was not sufficiently retained by the membrane, a set of homogeneous ruthenium-based catalysts were prepared to enhance the recovery, of the catalyst by solvent-resistant commercial membranes made of polyimide (Star-mem 228). The molecular weights of the catalysts were gradually increased from 627 to 2195 g mol(-1), and recovery was found to increase from around 70% to 90% both in toluene and dimethyl carbonate. The most retained catalyst was then engaged in a series of model ring-closing metathesis reactions associated to a final nanofiltration step to recover and recycle the catalyst. Up to five cycles could be performed before a deterioration in the performance of the process was observed.
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