4.5 Article

Hydrodynamic Model for Plasmonics: A Macroscopic Approach to a Microscopic Problem

期刊

CHEMPHYSCHEM
卷 14, 期 6, 页码 1109-1116

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201200992

关键词

dielectric properties; electrons; optical properties; plasma chemistry; nanoparticles

资金

  1. Air Force Office of Scientific Research [FA9550-09-1-0562]
  2. Army Research Office through a Multidisciplinary University Research Initiative [W911NF-09-1-0539]

向作者/读者索取更多资源

In this concept, we present the basic assumptions and techniques underlying the hydrodynamic model of electron response in metals and demonstrate that the model can be easily incorporated into computational models. We discuss the role of the additional boundary conditions that arise due to nonlocal terms in the modified equation of motion and the ultimate impact on nanoplasmonic systems. The hydrodynamic model captures much of the microscopic dynamics relating to the fundamental quantum mechanical nature of the electrons and reveals intrinsic limitations to the confinement and enhancement of light around nanoscale features. The presence of such limits is investigated numerically for different configurations of plasmonic nanostructures.

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