期刊
CHEMPHYSCHEM
卷 14, 期 16, 页码 3822-3826出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201300622
关键词
energy storage; flexible capacitors; gel electrolytes; nanotubes; paper electrodes
资金
- Department of Technology (DST), Government of India
A low-cost polyester cellulose paper has been used as a substrate for a flexible supercapacitor device that contains aqueous carbon nanotube ink as the electrodes and a polyvinyl alcohol (PVA)-based gel as the electrolyte. Gel electrolytes have attracted much interest due to their solvent-holding capacity and good film-forming capability. The electrodes are characterized for their conductivity and morphology. Because of its high conductivity, the conductive paper is studied in supercapacitor applications as active electrodes and as separators after coating with polyvinylidene fluoride. Carbon nanotubes deposited on porous paper are more accessible to ions in the electrolyte than those on flat substrates, which results in higher power density. A simple fabrication process is achieved and paper supercapacitors are tested for their performance in both aqueous and PVA gel electrolytes by using galvanostatic and cyclic voltammetry methods. A high specific capacitance of 270 Fg(-1) and an energy density value of 37 Whkg(-1) are achieved for devices with PVA gel electrolytes. Furthermore, this device can maintain excellent specific capacitance even under high currents. This is also confirmed by another counter experiment with aqueous sulfuric acid as the electrolyte. The cycle life, one of the most critical parameters in supercapacitor operations, is found to be excellent (6000 cycles) and less than 0.5% capacitance loss is observed. Moreover, the supercapacitor device is flexible and even after twisting does not show any cracks or evidence of breakage, and shows almost the same specific capacitance of 267 Fg(-1)and energy density of 37 Whkg(-1). This work suggests that a paper substrate can be a highly scalable and low-cost solution for high-performance supercapacitors.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据