期刊
CHEMPHYSCHEM
卷 14, 期 9, 页码 1956-1968出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201300086
关键词
binary mixtures; ionic liquids; mixing rules; modelling; viscosity
资金
- FCT [FCT/SFRH/BPD/34146, PTDC/CTM-NAN/121274/2010, PTDC/QUI-QUI/117340/2010, FCT-ANR/CTM-NAN/0135/2012]
- FP7-People-2010-IRSES Programme (NARILAR-New Working Fluids based on Natural Refrigerants and Ionic Liquids for Absorption Refrigeration) [269321]
In this work the applicability of four of the most commonly used viscosity mixing rules to [ionic liquid (IL)+molecular solvent (MS)] systems is assessed. More than one hundred (IL+MS) binary mixtures were selected from the literature to test the viscosity mixing rules proposed by 1) Hind (Hi), 2) Grunberg and Nissan (G-N), 3) Herric (He) and 4) Katti and Chaudhri (K-C). The analyses were performed by estimating the average (absolute or relative) deviations, AADs and ARDs, between the available experimental data and the predicted ideal mixture viscosity values obtained by means of each rule. The interaction terms corresponding to the adjustable parameters inherent to each rule were also calculated and their trends discussed.
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