期刊
CHEMPHYSCHEM
卷 14, 期 15, 页码 3441-3446出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201300402
关键词
bioluminescence; oxyluciferin; photoacids; proton transfer; tautomerism
资金
- Fundacao para Ciencia e Tecnologia (FCT, Lisbon) (Programa Operacional Tematico Factores de Competitividade (COMPETE) e comparticipado pelo Fundo Comunitario Europeu (FEDER) [PTDC/QUI/71366/2006]
- Israel Science Foundation
- James-Franck German-Israeli Program in Laser-Matter Interaction
The oxyluciferin family of fluorophores has been receiving much attention from the research community and several systematic studies have been performed in order to gain more insight regarding their photophysical properties and photoprotolytic cycles. In this minireview, we summarize the knowledge obtained so far and define several possible lines for future research. More importantly, we analyze the impact of the discoveries on the firefly bioluminescence phenomenon made so far and explain how they re-open again the discussion regarding the identity (keto or enol species) of the bioluminophore.
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