期刊
CHEMPHYSCHEM
卷 14, 期 14, 页码 3278-3283出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201300471
关键词
electron transfer; gold; iron; magnetic properties; nanoparticles
Plasmonic Au and magnetic Fe are coupled into uniform Au@Fe core-shell nanoparticles (NPs) to confirm that electron transfer occurred from the Au core to the Fe shell. Au NPs synthesized in aqueous medium are used as seeds and coated with an Fe shell. The resulting Au@Fe NPs are characterized by using various analytical techniques. X-ray photoelectron spectroscopy and superconducting quantum interference device measurements reveal that the Fe shell of the Au@Fe NPs mainly consists of paramagnetic Wustite with a thin surface oxide layer consisting of maghemite or magnetite. Electron transfer from the Au core to the Fe shell effectively suppresses iron oxidation from Fe2+ to Fe3+ near the interface between the Au and the Fe. The charge-transfer-induced electronic modification technique enables us to control the degree of iron oxidation and the resulting magnetic properties.
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