4.5 Article

ZnO/Co3O4 Porous Nanocomposites Derived from MOFs: Room-Temperature Ferromagnetism and High Catalytic Oxidation of CO

期刊

CHEMPHYSCHEM
卷 14, 期 17, 页码 3953-3959

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201300807

关键词

catalysis; magnetism; metal-organic framework; nanocomposite; oxides

资金

  1. National Natural Science Foundation (NSFC) [21071137]
  2. Foundation of National Science Base [J1030412]
  3. China Postdoctoral Science Foundation [2012M521261]

向作者/读者索取更多资源

ZnO/Co3O4 porous nanocomposites were successfully fabricated by the thermal decomposition of Prussian Blue analogue (PBA) Zn-3[Co(CN)(6)](2) nanospheres obtained at room temperature. Interestingly, ZnO/Co3O4 porous nanocomposites exhibit room-temperature ferromagnetism. Moreover, the ZnO/Co3O4 porous nanocomposites show good catalytic activity for CO oxidation, and the CO conversion rate reaches 100% at 250 degrees C. It is suggested that the synergistic effect of each component, relative high surface area (32 m(2) g(-1)) and porous structure lead to the promising catalytic properties.

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