期刊
CHEMPHYSCHEM
卷 12, 期 18, 页码 3539-3546出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201100379
关键词
ionic liquids; IR spectroscopy; liquid crystals; materials science; phase transitions
资金
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
The influence of confinement on the ionic liquid crystal (ILC) [C18C1Im][OTf] is studied using differential scanning calorimetry (DSC), polarized optical microscopy (POM), and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The ILC studied is supported on Si-based powders and glasses with pore sizes ranging from 11 to 50 nm. The temperature of the solid-to-liquid-crystalline phase transition seems mostly unaffected by the confinement, whereas the temperature of the liquid-crystalline-to-liquid phase transition is depressed for smaller pore sizes. A contact layer with a thickness in the order of 2 nm is identified. The contact layer exhibits a phase transition at a temperature 30 K lower than the solid-to-liquid-crystalline phase transition observed for the neat ILC. For applications within the supported ionic liquid phase (SILP) concept, the experiments show that in pores of diameter 50 nm a pore filling of a>0.4 is sufficient to reproduce the phase transitions of the neat ILC.
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