期刊
CHEMPHYSCHEM
卷 12, 期 12, 页码 2207-2215出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201100129
关键词
nanoparticles; oxides; phase equilibria; surface energy; thermodynamics
资金
- U.S. Department of Energy
- National Science Foundation
Because different solid materials (phases) have different surface energies, equilibria among them will be significantly affected by particle size. This Minireview summarizes experimental (calorimetric) data for the surface energies of oxides and discusses shifts in the stability of polymorphs, the thermodynamics of hydration, and oxidation-reduction reactions in nanoscale oxide systems.
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