期刊
CHEMPHYSCHEM
卷 11, 期 17, 页码 3673-3677出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201000723
关键词
ionic liquids; ion cyclotron resonance spectrometry; mass spectrometry; molecular dynamics; thermodynamics
资金
- FCT/Portugal [PTDC/QUI/66199/2006, PTDC/QUI-QUI/101794/2008]
- [SFRH/BPD/38339/2007]
- [SFRH/PD/70201/2010]
- Fundação para a Ciência e a Tecnologia [PTDC/QUI/66199/2006] Funding Source: FCT
- Engineering and Physical Sciences Research Council [EP/D073014/1] Funding Source: researchfish
- EPSRC [EP/D073014/1] Funding Source: UKRI
The vaporization of a dicationic ionic liquid at moderate temperatures and under reduced pressures -recently studied by line-of-sight mass spectrometry-was further analyzed using an ion-cyclotron resonance mass spectroscopy technique that allows the monitoring of the different species present in the gas phase through the implementation of controlled ion-molecule reactions. The results support the view that the vapour phase of an aprotic dicationic ionic liquid is composed of neutral ion triplets (one dication attached to two anions). Molecular dynamics simulations were also performed in order to explain the magnitude of the vaporization enthalpies of dicationic ionic liquids vis-a-vis their monocationic counterparts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据