期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 29, 页码 8440-8443出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201502026
关键词
mechanochemistry; reactive intermediates; thiocarbamoylation; thiourea
资金
- Canadian Foundation for Innovation (CFI)
- NSERC
- NRC Canada
- Canadian Institutes of Health Research
- Government of Saskatchewan
- Western Economic Diversification Canada
- University of Saskatchewan
- FRQNT Nouveaux Chercheurs grant
- McGill University
Monitoring of mechanochemical thiocarbamoylation by in situ Raman spectroscopy revealed the formation of aryl N-thiocarbamoylbenzotriazoles, reactive intermediates deemed unisolable in solution. The first-time isolation and structural characterization of these elusive molecules demonstrates the ability of mechanochemistry to access otherwise unobtainable intermediates and offers a new range of masked isothiocyanate reagents.
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