期刊
CHEMOSPHERE
卷 82, 期 2, 页码 278-283出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2010.09.033
关键词
Chitosan iron complex; As(III); Adsorption isotherm; Mossbauer spectroscopy
资金
- ProPEC
- CNPq
- FAPESC [03/2006]
It was reported the adsorption of As(III) on the surface of the chitosan-Fe-crosslinked complex. Theoretical correlation of the experimental equilibrium adsorption data for As(III)/Ch-Fe system is best explained by the non-linearized form Langmuir-Freundlich isotherm model. At optimum conditions, pH 9.0, the maximum adsorption capacity, calculated using the Langmuir-Freundlich isotherm model was 13.4 mg g(-1). The adsorption kinetics of As(III) onto Ch-Fe are described by the pseudo-first-order kinetic equation. The results of the Mossbauer spectroscopy showed that there is no redox process on the surface of the adsorbent. (C) 2010 Elsevier Ltd. All rights reserved.
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