期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 10, 期 1, 页码 96-99出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201403097
关键词
alkoxylation; alkylation; copper catalysis; difunctionalization; radicals
A simple copper-catalyzed direct radical carbooxygenation of styrenes is developed utilizing alkyl bromides as radical resources. This catalytic radical difunctionalization accomplishes both alkylation and alkoxylation of styrenes in one pot. A broad range of styrenes and alcohols are well tolerated in this transformation. The EPR experiment shows that alkyl halides could oxidize Cu(I) to Cu(II) in this transformation.
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