期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 9, 期 11, 页码 3116-3120出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201402777
关键词
in-situ synthesis; magnetic properties; magnetocaloric effect; organic-inorganic hybride composites; stability
资金
- 973 Program of China [2014CB845600, 2012CB821700]
- NSF of China [21031002, 21290171]
- MOE Innovation Team of China [IRT13022]
A dense and stable inorganic-organic hybrid with distorted cubic [Gd4O4] units as building blocks bridged by in situ generated sulfate and oxalate was synthesized. Magnetic measurements indicate that the title complex features a -Delta S-m(max) = 51.49 Jkg(-1)K(-1), which is among the highest values reported so far.
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