期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 9, 期 8, 页码 2140-2147出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201402142
关键词
catalysis; hydrogen; iron; organometallic complexes; silylation
资金
- Beilstein-Stiftung
A series of defined iron-hydrogen complexes was prepared in a straightforward one-pot approach. The structure and electronic properties of such complexes were investigated by means of quantum-chemical analysis. These new complexes were then applied in the dehydrogenative silylation of methanol. The complex (dppp)(CO)(NO)FeH showed a remarkable activity with a TOF of more than 600 000 h(-1) of pure hydrogen gas within seconds.
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