期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 9, 期 2, 页码 572-576出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201301209
关键词
cobalt sulfide; lithium-ion batteries; mesoporous materials; nanostructures; spray pyrolysis; sulfur
资金
- National Research Foundation of Korea (NRF)
- Korean government (MEST) [2012R1A2A2A02046367]
- National Research Foundation of Korea [22A20130012144, 2012R1A2A2A02046367] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
In this study, we report the first preparation of phase-pure Co9S8 yolk-shell microspheres in a facile two-step process and their improved electrochemical properties. Yolk-shell Co3O4 precursor microspheres are initially obtained by spray pyrolysis and are subsequently transformed into Co9S8 yolk-shell microspheres by simple sulfidation in the presence of thiourea as a sulfur source at 350 degrees C under a reducing atmosphere. For comparison, filled Co9S8 microspheres were also prepared using the same procedure but in the absence of sucrose during the spray pyrolysis. The prepared yolk-shell Co9S8 microspheres exhibited a Brunauer-Emmett-Teller (BET) specific surface area of 18m(2)g(-1) with a mean pore size of 16nm. The yolk-shell Co9S8 microspheres have initial discharge and charge capacities of 1008 and 767mAhg(-1) at a current density of 1000mAg(-1), respectively, while the filled Co9S8 microspheres have initial discharge and charge capacities of 838 and 638mAhg(-1), respectively. After 100cycles, the discharge capacities of the yolk-shell and filled microspheres are 634 and 434mAhg(-1), respectively, and the corresponding capacity retentions after the first cycle are 82% and 66%.
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